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http://hdl.handle.net/10884/1329| Título: | A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine |
| Autores: | Figueiredo, Paulo Pina, Fernando |
| Data: | Jul-1988 |
| Citação: | Journal of Photochemistry and Photobiology A: Chemistry, Vol. 44, pages 57-61 |
| Resumo: | A photocatalytic cycle based on the ion pair Co(sep)3+·I− (sep sepulchrate 1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6] eicosane)), in which substrates easily oxidizable by iodine are oxidized by dioxygen, is described. A direct relation between the ion pair charge transfer band maximum and the one-electron redox potential of the corresponding anion was verified. Possible applications of these cycles, such as energy conversion, are discussed. |
| URI: | http://hdl.handle.net/10884/1329 |
| Aparece nas colecções: | A CS/CN - Artigos |
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