Please use this identifier to cite or link to this item: http://hdl.handle.net/10884/496
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dc.contributor.authorElhabiri, Mourad-
dc.contributor.authorFigueiredo, Paulo-
dc.contributor.authorGeorge, Florian-
dc.contributor.authorCornard, Jean-Paul-
dc.contributor.authorFougerousse, André-
dc.contributor.authorMerlin, Jean-Claude-
dc.contributor.authorBrouillard, Raymond-
dc.date.accessioned2012-03-06T15:07:00Z-
dc.date.available2012-03-06T15:07:00Z-
dc.date.issued1996-
dc.identifier.citationCan. J. Chem. 74: 697-706pt_PT
dc.identifier.urihttp://hdl.handle.net/10884/496-
dc.description.abstractA series of five, structurally related, substituted 2-phenyl-benzopyrylium (flavylium) salts were synthesized and characterized by NMR, absorption, and fluorescence techniques. Their hydration and deprotonation constants were obtained through thermodynamic and relaxation kinetic methods. Metallic complexation with the two compounds possessing a catechol group and its effect on the fluorescence intensity was also studied. The ground state properties of the five pigments are correlated with the theoretical data collected through AM1 molecular orbital calculations.pt_PT
dc.language.isoengpt_PT
dc.rightsopenAccessen
dc.subjectNaphtoflavyliumpt_PT
dc.subjectHydration and deprotonation constantspt_PT
dc.subjectFluorescencept_PT
dc.subjectMetallic complexationpt_PT
dc.subjectMolecular orbital calculationspt_PT
dc.titleGround- and excited-state properties of some naphthoflavyliumspt_PT
dc.typearticlept_PT
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