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Title: A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
Authors: Figueiredo, Paulo
Pina, Fernando
Issue Date: Jul-1988
Citation: Journal of Photochemistry and Photobiology A: Chemistry, Vol. 44, pages 57-61
Abstract: A photocatalytic cycle based on the ion pair Co(sep)3+·I− (sep  sepulchrate  1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6] eicosane)), in which substrates easily oxidizable by iodine are oxidized by dioxygen, is described. A direct relation between the ion pair charge transfer band maximum and the one-electron redox potential of the corresponding anion was verified. Possible applications of these cycles, such as energy conversion, are discussed.
Appears in Collections:A CS/CN - Artigos

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